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- W2045803239 abstract "Polystyrene microfibers containing lower-rim substituted calix[4]arene with phosphinoyl pendant arms were easily prepared in one-step procedure by electrospinning. A specific feature of the fibers is the difference in their functionality at the surface and in the bulk. The graded structure of the fibers was shown by XPS analyses. The calix[4]arene concentration in the 3-5 nm surface layer was 50% higher than the theoretically calculated if calix[4]arene was uniformly distributed in the fibers. A six-coordinated complex was formed between the calix[4]arene included in the fibers and Ni 2+ ions. The distribution of phosphorus along the fibers is uniform, as evidenced by X-ray mapping." @default.
- W2045803239 created "2016-06-24" @default.
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- W2045803239 date "2008-12-01" @default.
- W2045803239 modified "2023-09-24" @default.
- W2045803239 title "One-Step Preparation of Electrospun Microfibrous Polystyrene Mats Having Surface Enriched inp-tert-Butylcalix[4]arene Fitted with Phosphinoyl Pendant Arms" @default.
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- W2045803239 doi "https://doi.org/10.1002/marc.200800438" @default.
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