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- W2045804219 abstract "The action of diethyl malonate and ethyl cyanoacetate on dimethyl(triethylgermyl)amine has been studied. In both cases, competition between two reactions is observed: a cleavage reaction of the germanium-nitrogen bond by these reagents and an addition reaction on to the carbonyl group of an ester function. The cleavage reaction of the Ge-N bond leads to the corresponding β-functional C-germanium derivatives: ethyl C-(triethylgermyl)malonate and ethyl C-(triethylgermyl)cyanoacetate, thermally stable. The addition reactions on the carbonyl group of ester functions lead to new thermally unstable β-functional α-aminoalkoxygermanes. These last reactions are compared with those obtained with ethyl acetate or ethylenic esters. The thermal decomposition of β-functional α-aminoalkoxygermanes formed in the course of these reactions has been studied, and leads mainly to alkoxygermanes and the corresponding β-functional amide by an intramolecular decomposition process." @default.
- W2045804219 created "2016-06-24" @default.
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- W2045804219 date "2010-09-02" @default.
- W2045804219 modified "2023-10-14" @default.
- W2045804219 title "Réactivité des germylamines vis à vis de certains esters. Obtention de dérivés germaniés β-difonctionnels" @default.
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- W2045804219 doi "https://doi.org/10.1002/recl.19750940110" @default.
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