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- W2045808210 abstract "Abstract The nascent OH rovibrational distribution for the reaction CH4·O3+hν266 nm→CH3+OH+O2 are reported. The population ratio between the vibrational levels was found to be ν(0)/ν(1) = 1.0±0.2 (2σ), ν(1)/ν(2) = 0.67±0.26, and ν(2)/ν(3) = 1.5±0.2; and significant rotational excitation was observed for all vibrational states. The asymmetric lambda doublet is populated to a greater extent than expected statistically, but no measurable spin—orbit propensity was observed. Both the rotational and vibrational distributions are somewhat cooler than those of the analogous ‘free’ reaction, CH4+O(1D2)→CH3+OH." @default.
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- W2045808210 date "1994-06-01" @default.
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- W2045808210 title "OH (ν, J) distributions from the reaction between CH4 and O (1D2), initiated in CH4·O3 clusters" @default.
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- W2045808210 doi "https://doi.org/10.1016/0009-2614(94)00445-5" @default.
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