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- W2045810367 abstract "While permanent magnets based on Sm1Co5 are technologically important, magnets made from isostructural Pr1Co5 are not commercially significant even though Pr1Co5 has better intrinsic magnetic properties. The biggest problem is the formation of unfavorable phase equilibria which leads to an inability to develop high coercivity in binary Pr–Co alloys. A proposed solution was to make a hyperstoichiometric alloy with Gd as a substitute, in addition to carbon, to inhibit the formation of the deleterious phases leading to a predominantly single magnetic phase composition. An enhancement was observed in the coercivity. This result is perhaps surprising considering that the Gd atom, with a spherical 4f electron shell, is not expected to contribute to the magnetocrystalline anisotropy. Thus, the expectation was that the coercivity increase was caused by the microstructure but no distinguishing feature of microstructure was observed in transmission electron microscopy. It appears that Gd substitution instead affects the intrinsic magnetocrystalline anisotropy by reducing the effect of the small canting of the Pr moment through dilution." @default.
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- W2045810367 date "2003-05-09" @default.
- W2045810367 modified "2023-10-13" @default.
- W2045810367 title "Developing highly coercive microstructures in Pr–Co magnets by Gd substitution" @default.
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- W2045810367 doi "https://doi.org/10.1063/1.1541656" @default.
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