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- W2045852611 abstract "Using thermoelectricity to directly convert (waste) heat energy into useful electricity faces a number of challenges. Not only are optimised thermal and electrical transport properties required resulting in a high figure of merit ZT and a high thermal–electric conversion efficiency η over a wide temperature range, thermoelectric (TE) materials must have sufficient mechanical integrity to survive continuous heating–cooling cycles. Thermal expansion of the material as well as the mechanical properties play an important role, i.e. their values should be as similar as possible for p- and n-type alloys to avoid stresses when used in a TE device. In this paper multiple filled p- and n-type skutterudites (Ba,Sr,DD,Yb) y (Fe 1– x Ni x ) 4 Sb 12 with a ZT > 1 and η ≈ 13% are presented, for the first time showing, in contrast to hitherto investigated skutterudites, nearly identical thermal expansion coefficients and elastic moduli. The ZT values of these skutterudites could be further enhanced by more than 20% after severe plastic deformation via high-pressure torsion." @default.
- W2045852611 created "2016-06-24" @default.
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- W2045852611 date "2013-06-01" @default.
- W2045852611 modified "2023-09-26" @default.
- W2045852611 title "New p- and n-type skutterudites with ZT>1 and nearly identical thermal expansion and mechanical properties" @default.
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- W2045852611 doi "https://doi.org/10.1016/j.actamat.2013.03.031" @default.
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