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- W2045877527 abstract "The title compound, Ca[Sn(H2PO2)6], was formed after a few days when tin(II) fluoride was allowed to react with phosphinic acid at ambient conditions. The structure consists of chains of Ca(2+) and Sn(4+) cations in octa-hedral sites with -3 symmetry bridged by bidentate hypophosphite anions. The chains are hexa-gonally close packed along [001]. The discovery of the compound and the successful structure refinement provides strong evidence that an isostructural compound, originally described as the mixed-valence compound, Ge2[H2PO2]6 [Weakley (1983 ▶). J. Chem. Soc. Pak. 5, 279-281], must be reformulated as Ca[Ge(H2PO2)6]." @default.
- W2045877527 created "2016-06-24" @default.
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- W2045877527 date "2013-07-06" @default.
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- W2045877527 title "Calcium hexakis(dihydrogenphosphito)stannate(IV), Ca[Sn(H<sub>2</sub>PO<sub>2</sub>)<sub>6</sub>], with some remarks on the so-called Ge<sub>2</sub>(H<sub>2</sub>PO<sub>2</sub>)<sub>6</sub>structure type" @default.
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- W2045877527 doi "https://doi.org/10.1107/s1600536813018205" @default.
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