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- W2045884060 abstract "Abstract We predict that photocyclization of trans-stilbene to 4a,4b-dihydrophenanthrene (DHP) can be achieved with a femtosecond-scale laser pulse. Specifically, we have performed dynamical simulations in which the original trans-stilbene molecule is observed first to isomerize to cis-stilbene (as an excited-state intermediate) after more than one picosecond, and then to form a new bond to become DHP, after a few hundred additional femtoseconds. The process is initiated by excitation from the S 0 electronic state to S 1 , with subsequent de-excitation at avoided crossings." @default.
- W2045884060 created "2016-06-24" @default.
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- W2045884060 date "2010-03-01" @default.
- W2045884060 modified "2023-10-15" @default.
- W2045884060 title "Photocyclization of trans-stilbene induced by an ultrafast laser pulse" @default.
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- W2045884060 doi "https://doi.org/10.1016/j.cplett.2010.01.035" @default.
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