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• W2045885216 startingPage "20781" @default.
• W2045885216 abstract "Aerosol OT/water exhibits a lamellar phase over a wide range of concentrations. We show, by magnetic resonance (NMR) and scanning electron microscopy (SEM), that the morphology of the lamellar phase varies significantly across that range and that the rate of equilibration depends strongly on concentration (25, 33, and 50 wt %) with, paradoxically, the faster equilibration at higher surfactant concentrations. We find that the 25 wt % sample exhibits a defect-rich local structure, characteristic of a superposed L3 character. Further into the lamellar region, at 33 wt %, this defect-rich structure persists heterogeneously, while, at 50 wt %, the lamellar phase domains are highly ordered. The NMR methods used here included 2H spectroscopy and the two-dimensional NMR method, diffusion−diffusion exchange spectroscopy (DEXSY). The latter was used to obtain quantitative information on the domain sizes and defects within the polydomain lamellar mesophase. Comparison of the NMR with the SEM results suggests that, at 25 wt % AOT, bilayer defects play an important role in influencing the 2H NMR and DEXSY NMR results." @default.
• W2045885216 created "2016-06-24" @default.
• W2045885216 creator A5013534739 @default.
• W2045885216 creator A5049302548 @default.
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• W2045885216 date "2006-10-01" @default.
• W2045885216 modified "2023-09-27" @default.
• W2045885216 title "Evolution of a Lamellar Domain Structure for an Equilibrating Lyotropic Liquid Crystal" @default.
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• W2045885216 doi "https://doi.org/10.1021/jp0601872" @default.
• W2045885216 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17048887" @default.
• W2045885216 hasPublicationYear "2006" @default.
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