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• W2045888254 abstract "The infrared- and Raman-active vibrational modes of ${mathrm{C}}_{60}$ were measured in the various structural states of ${mathrm{RbC}}_{60}$. According to earlier studies, ${mathrm{RbC}}_{60}$ has an fcc structure at temperatures above ensuremath{sim}100 ifmmode^circelsetextdegreefi{}C, a linear chain polymer orthorhombic structure when slowly cooled, and an as yet undetermined structure when very rapidly cooled (``quenched''). We show that the spectra obtained in the polymer state are consistent with each ${mathrm{C}}_{60}$ molecule having bonds to two diametrically opposite neighbors. In the quenched state, we find evidence for further symmetry breaking, implying a lower symmetry structure than the polymer state. The spectroscopic data of the quenched phase are shown to be consistent with ${mathrm{Rb}}_{2}$(${mathrm{C}}_{60}$${)}_{2}$, a dimerization of ${mathrm{C}}_{60}$." @default.
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• W2045888254 date "1995-02-01" @default.
• W2045888254 modified "2023-10-17" @default.
• W2045888254 title "Infrared and Raman evidence for dimers and polymers in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>RbC</mml:mi></mml:mrow><mml:mrow><mml:mn>60</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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• W2045888254 doi "https://doi.org/10.1103/physrevb.51.3210" @default.
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