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- W2045888945 abstract "On a préparé une série de dérivés du bicyclo[2.2.2]octane de configurations absolues connues par corrélation chimique avec des produits de référence confirmés (bicyclo[2.2.2]octanol, acide bicyclo[2.2.2]-octène carboxylique). La 1 (R) carbométhoxy-2(S) bicyclo[2.2.2]octanone-6 et la dicarbométhoxy-2(S)3(S) bicyclo[2.2.2]-octanone-6 présentent un dichroïsme circulaire inverse de celui que prévoit la règle des octants. Par contre, dans cette série, la méthode d'Horeau fournit des résultats cohérents et exacts. A series of bicyclo[2.2.2]octane derivatives whose absolute configurations are known through chemical correlations with confirmed reference products (bicyclo[2.2.2]octanol, bicyclo[2.2.2]octene carboxylic acid) have been prepared. 1 (R) 2 (S)-carbomethoxy bicyclo[2.2.0]octan-6-one and 2 (S) 3 (S)-dicarbomethoxy bicyclo[2.2.2]octan-6-one show a circular dichroïsm opposite to that which is predicted by octant's rule. On the contrary, in this series, Horeau's method gives coherent and exact results." @default.
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- W2045888945 date "1972-01-01" @default.
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- W2045888945 title "Determination de la configuration absolue de quelques derives du bicyclo[2.2.2]octane: Utilisation comparee de la regle des octants et de la methode d'horeau" @default.
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- W2045888945 doi "https://doi.org/10.1016/s0040-4020(01)93632-4" @default.
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