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- W2045889092 abstract "The effect of alkali metal cationization on the collision-induced decomposition of alkyl per-O-acetyl-2-deoxy-2-bromo-and-iodo-α-O-mannopyranosides was studied. The bromo sugars gave fairly abundant MH+, whereas for the iodo sugars the MH+ ions were insignificant. However, both the bromo and the iodo derivatives gave abundant M + alkali metal ion complexes. In contrast to the behaviour of the MH+ ion, the [M + Li]+, [M + Na]+ and [M + K]+ ions of these compounds do not decompose by loss of the C(1) substituent. Elimination of AcOH is the preferred fragmentation pathway of [M + Cat]+. Elimination of HX occurs only after loss of AcOH and CH2CO from MH+, whereas [M + Cat]+ directly loses HX. The elimination of HX is more pronounced from [M + Na]+ and [M + K]+ than from [M + Li]+. Loss of AcOLi is an additional fragmentation route observed in the case of the decomposition of [M + Li]+ ion." @default.
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- W2045889092 date "1993-08-01" @default.
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- W2045889092 title "Effect of alkali metal cationization on the collision-induced decomposition of alkyl per-O-acetyl-2-deoxy-2-halo-α-O-mannopyranosides" @default.
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- W2045889092 doi "https://doi.org/10.1002/oms.1210280812" @default.
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