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- W2045909968 abstract "The chemical grafting of alkanethiol-terminated poly(ethylene glycol) to a gold substrate from dimethylformamide solution was monitored by in situ ellipsometry for several molar concentrations. In the initial stage a layer of mushroom-like moieties forms and, on a much longer time scale, is followed by conformational conversion (and further adsorption) to a dense brush of stretched polymers. A statistical mechanical theory is presented that allows for a nonuniform grafting density and conformational conversion. It accounts fully for all observed details." @default.
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- W2045909968 date "2003-11-01" @default.
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- W2045909968 title "Growth of a dense polymer brush layer from solution" @default.
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- W2045909968 doi "https://doi.org/10.1209/epl/i2003-00205-7" @default.
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