FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045912737> ?p ?o ?g. }

• W2045912737 endingPage "909" @default.
• W2045912737 startingPage "905" @default.
• W2045912737 abstract "Photoswitches incorporated into molecular frameworks have been used since a long time to trigger chemical processes on demand. Here, it is shown how mechanophores can be used as switches in order to drastically change the reactivity of a neighboring functional group as a function of external stress. The reactivities of cyclic enediynes, which are highly toxic agents when undergoing Bergman cyclization, roughly correlate with the distance between the bond-forming carbons in many cases. It is demonstrated how this distance, and thus enediyne reactivity, can be tuned upon applying mechanical stress. Depending on suitable substitution patterns, chemically inert species can be turned into highly reactive ones and vice versa, thus extending the concept of photoswitching to mechanoswitching. Moreover, depending on the derivative, it is found that C1-C5 cyclization becomes energetically preferred over the Bergman (C1-C6) pathway at nano-Newton forces, thus leading to a force-induced switch in selectivity in such cases." @default.
• W2045912737 created "2016-06-24" @default.
• W2045912737 creator A5044135877 @default.
• W2045912737 creator A5052891474 @default.
• W2045912737 creator A5072717593 @default.
• W2045912737 date "2014-02-20" @default.
• W2045912737 modified "2023-09-23" @default.
• W2045912737 title "Mechanical Manipulation of Chemical Reactions: Reactivity Switching of Bergman Cyclizations" @default.
• W2045912737 cites W1968241942 @default.
• W2045912737 cites W1970013669 @default.
• W2045912737 cites W1979274326 @default.
• W2045912737 cites W1993734537 @default.
• W2045912737 cites W1996720874 @default.
• W2045912737 cites W1997504607 @default.
• W2045912737 cites W1997661314 @default.
• W2045912737 cites W2012666555 @default.
• W2045912737 cites W2025370930 @default.
• W2045912737 cites W2026834933 @default.
• W2045912737 cites W2028316611 @default.
• W2045912737 cites W2033536294 @default.
• W2045912737 cites W2033972881 @default.
• W2045912737 cites W2043008468 @default.
• W2045912737 cites W2044764284 @default.
• W2045912737 cites W2046074550 @default.
• W2045912737 cites W2047182279 @default.
• W2045912737 cites W2048369597 @default.
• W2045912737 cites W2048948454 @default.
• W2045912737 cites W2051769448 @default.
• W2045912737 cites W2056189301 @default.
• W2045912737 cites W2058128681 @default.
• W2045912737 cites W2062830327 @default.
• W2045912737 cites W2065630802 @default.
• W2045912737 cites W2083463266 @default.
• W2045912737 cites W2083827540 @default.
• W2045912737 cites W2086650661 @default.
• W2045912737 cites W2095610691 @default.
• W2045912737 cites W2095859689 @default.
• W2045912737 cites W2097500559 @default.
• W2045912737 cites W2120631400 @default.
• W2045912737 cites W2123155551 @default.
• W2045912737 cites W2132658163 @default.
• W2045912737 cites W2949262469 @default.
• W2045912737 cites W2950068262 @default.
• W2045912737 cites W2952340219 @default.
• W2045912737 doi "https://doi.org/10.1021/jz402644e" @default.
• W2045912737 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26274086" @default.
• W2045912737 hasPublicationYear "2014" @default.
• W2045912737 type Work @default.
• W2045912737 sameAs 2045912737 @default.
• W2045912737 citedByCount "11" @default.
• W2045912737 countsByYear W20459127372014 @default.
• W2045912737 countsByYear W20459127372015 @default.
• W2045912737 countsByYear W20459127372017 @default.
• W2045912737 countsByYear W20459127372018 @default.
• W2045912737 countsByYear W20459127372019 @default.
• W2045912737 crossrefType "journal-article" @default.
• W2045912737 hasAuthorship W2045912737A5044135877 @default.
• W2045912737 hasAuthorship W2045912737A5052891474 @default.
• W2045912737 hasAuthorship W2045912737A5072717593 @default.
• W2045912737 hasConcept C106159729 @default.
• W2045912737 hasConcept C111771559 @default.
• W2045912737 hasConcept C142724271 @default.
• W2045912737 hasConcept C147597530 @default.
• W2045912737 hasConcept C154256306 @default.
• W2045912737 hasConcept C159467904 @default.
• W2045912737 hasConcept C162324750 @default.
• W2045912737 hasConcept C171250308 @default.
• W2045912737 hasConcept C178790620 @default.
• W2045912737 hasConcept C185592680 @default.
• W2045912737 hasConcept C192562407 @default.
• W2045912737 hasConcept C204787440 @default.
• W2045912737 hasConcept C2776910235 @default.
• W2045912737 hasConcept C2777566158 @default.
• W2045912737 hasConcept C71240020 @default.
• W2045912737 hasConcept C71924100 @default.
• W2045912737 hasConceptScore W2045912737C106159729 @default.
• W2045912737 hasConceptScore W2045912737C111771559 @default.
• W2045912737 hasConceptScore W2045912737C142724271 @default.
• W2045912737 hasConceptScore W2045912737C147597530 @default.
• W2045912737 hasConceptScore W2045912737C154256306 @default.
• W2045912737 hasConceptScore W2045912737C159467904 @default.
• W2045912737 hasConceptScore W2045912737C162324750 @default.
• W2045912737 hasConceptScore W2045912737C171250308 @default.
• W2045912737 hasConceptScore W2045912737C178790620 @default.
• W2045912737 hasConceptScore W2045912737C185592680 @default.
• W2045912737 hasConceptScore W2045912737C192562407 @default.
• W2045912737 hasConceptScore W2045912737C204787440 @default.
• W2045912737 hasConceptScore W2045912737C2776910235 @default.
• W2045912737 hasConceptScore W2045912737C2777566158 @default.
• W2045912737 hasConceptScore W2045912737C71240020 @default.
• W2045912737 hasConceptScore W2045912737C71924100 @default.
• W2045912737 hasIssue "5" @default.
• W2045912737 hasLocation W20459127371 @default.
• W2045912737 hasLocation W20459127372 @default.
• W2045912737 hasOpenAccess W2045912737 @default.
• W2045912737 hasPrimaryLocation W20459127371 @default.
• W2045912737 hasRelatedWork W1976253167 @default.
• W2045912737 hasRelatedWork W2009996801 @default.

• next