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- W2045954277 endingPage "1773" @default.
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- W2045954277 abstract "The 2,2′-bi-1H-imidazole (H2BIM) derivatives were studied from the point of the interplay of proton-transfer (PT) and electron (charge)-transfer (CT) interactions. Seven new states among the speculated 25 independent species were identified based on the study of their redox and acid dissociation properties. Isoelectronic substitution of four sulfur atoms of the dication state of tetrathiafulvalene (TTF2+) by four imino groups was found to increase the stability of the dication state 2,2′-bi-1H-imidazolium (H4BIM2+) with aromatic 6π–6π character. The high PT character of H3BIM+ (2-(2-1H-imidazolyl)-1H-imidazolium) and H4BIM2+ compared with that of the corresponding hydroquinone system was clearly observed. The on-site Coulomb repulsion energy for electron-transfer (U1CT) was evaluated for various π-electron acceptor and donor systems. It was found that the U1CT values decrease linearly with increasing the length of a molecule, which can divide the molecular systems into two classifications, i.e. electron a..." @default.
- W2045954277 created "2016-06-24" @default.
- W2045954277 creator A5004167567 @default.
- W2045954277 creator A5053704070 @default.
- W2045954277 date "1995-07-01" @default.
- W2045954277 modified "2023-10-12" @default.
- W2045954277 title "Multiplex Proton-Transfer and Electron-Transfer Natures Based on the 2,2′-Bi-1<i>H</i>-imidazole System. I. Acid Dissociation Constants and Redox Properties in Solution" @default.
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- W2045954277 doi "https://doi.org/10.1246/bcsj.68.1753" @default.
- W2045954277 hasPublicationYear "1995" @default.
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