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- W2045967833 abstract "The electronic properties of copper-containing zinc phosphate glasses are investigated in the range of low copper concentrations as well as for variable ZnO/P2O5 ratios, in order to verify whether current polaronic theories of charge transport in disordered systems apply to glasses containing transition metal (TM) ions. Special emphasis is given in this paper to the analysis of the d.c. activation energy in the range 300-600 K, which is discussed also on the basis of spectroscopic and magnetic measurements. Support is provided to polaronic models in the range of temperatures where the activation energy is constant. Moreover, further indications of the local structure of the TM centers are obtained, which are found to well fit the theoretical frame. Major difficulties are met in the analysis of the intermediate temperature region (300-500 K), where only a qualitative agreement with model predictions is found. Tentative explanations of this discrepancy are given and a general discussion of current theories is presented." @default.
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- W2045967833 date "1988-07-01" @default.
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- W2045967833 title "Temperature-dependent activation energy for polaronic conduction in copper-doped zinc phosphate glasses" @default.
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- W2045967833 doi "https://doi.org/10.1088/0031-8949/38/1/016" @default.
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