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• W2045974417 abstract "The hydrogenation of carbon monoxide on molybdenum- and tugsten-promoted silica-supported rhodium catalysts has been investigated. Whereas preparation according to the conventional impregnation method leads to bimetallic catalysts with substantially increased activity in comparison to monometallic samples, the application of heteronuclear carbonyl clusters as precursors results additionally in an enhanced selectivity towards oxygen-containing products. Fourier transform infrared spectroscopy, hydrogen chemisorption and temperature programmed reduction have been used to characterize the samples. The results indicate that covering of the Rh by promoter oxide species occurs to a certain extent." @default.
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• W2045974417 date "1989-11-01" @default.
• W2045974417 modified "2023-09-23" @default.
• W2045974417 title "New bimetallic Rh-Mo and Rh-W clusters as precursors for selective heterogeneous co hydrogenation" @default.
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• W2045974417 doi "https://doi.org/10.1016/0304-5102(89)80175-0" @default.
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