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- W2045975044 abstract "The treatment of allylarylamines with mercury(II) acetate in tetrahydrofuran followed by a double decomposition reaction with potassium bromide leads to trans-2,5-bis(bromomercuriomethyl)-1,4-diarylpiperazines (2). The stereochemistry of the reaction products has been elucidated by an 1H-nmr spectroscopic study of the trans-2,5-dimethyl-1,4-diarylpiperazines (3) obtained by sodium borohydride reduction of 2 in alkaline media. The course of the reaction strongly depends on the steric demand of the groups attached to either the allylic group or the ortho-position in the aromatic ring of the starting amine (1)." @default.
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- W2045975044 date "1979-07-01" @default.
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- W2045975044 title "Stereoselective synthesis of substituted piperazines" @default.
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- W2045975044 doi "https://doi.org/10.1002/jhet.5570160536" @default.
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