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• W2045976589 abstract "A thermodynamic formalism is developed for illuminating the predominant point defect mechanism of self- and impurity diffusion in silicon and is used to provide a rigorous basis for point defect-based interpretation of diffusion experiments in biaxially strained epitaxial layers in the Si–Ge system. A specific combination of the hydrostatic and biaxial stress dependences of the diffusivity is ±1 times the atomic volume, depending upon whether the predominant mechanism involves vacancies or interstitials. Experimental results for Sb diffusion in biaxially strained Si–Ge films and ab initio calculations of the activation volume for Sb diffusion by a vacancy mechanism are in quantitative agreement with no free parameters. Key parameters are identified that must be measured or calculated for a quantitative test of interstitial-based mechanisms." @default.
• W2045976589 created "2016-06-24" @default.
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• W2045976589 date "1997-05-26" @default.
• W2045976589 modified "2023-10-11" @default.
• W2045976589 title "Thermodynamics of diffusion under pressure and stress: Relation to point defect mechanisms" @default.
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• W2045976589 doi "https://doi.org/10.1063/1.119066" @default.
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