Matches in SemOpenAlex for { <https://semopenalex.org/work/W2045979354> ?p ?o ?g. }
- W2045979354 endingPage "1823" @default.
- W2045979354 startingPage "1817" @default.
- W2045979354 abstract "The oxidative addition reaction of SnCl4 with [W(CO)4(NCMe)(PPh3)] in acetonitrile gives a mixture of seven-coordinate tungsten(II) compounds: [WCl(SnCl3)(CO)3(NCMe)(PPh3)] (1), [WCl2(CO)3(NCMe)(PPh3)] (2), [WCl(SnCl3)(CO)2(NCMe)2(PPh3)] (3), and [WCl2(CO)2(NCMe)2(PPh3)] (4) identified by IR and NMR (1H, 13C{1H}, and 31P{1H}) studies. Treatment of [W(CO)4(NCMe)(PPh3)] with 1 equiv. of SnCl4 in CH2Cl2 solution besides compounds 1 and 2 also gives ionic species such as [HPPh3]+ and [SnCl6]2− and cationic tungsten(II) complexes. The crystal structure of one of these, [WH(CO)3(NCMe)(PPh3)2][SnCl5·MeOH] (5), has been established by single-crystal X-ray diffraction. The IR, 1H, 13C{1H} and 31P{1H} spectra of 5 are also described and can be correlated with the crystallographically observed geometry. A notable feature of 5 is the presence of an agostic interaction of the hydride ligand with one of the carbonyl ligands." @default.
- W2045979354 created "2016-06-24" @default.
- W2045979354 creator A5057431845 @default.
- W2045979354 creator A5058540945 @default.
- W2045979354 creator A5060019697 @default.
- W2045979354 date "2002-08-01" @default.
- W2045979354 modified "2023-10-17" @default.
- W2045979354 title "The oxidative addition of SnCl4 to [W(CO)4(NCMe)(PPh3)]. The X-ray crystal structure of [WH(CO)3(NCMe)(PPh3)2][SnCl5·MeOH]" @default.
- W2045979354 cites W1595006058 @default.
- W2045979354 cites W1964004028 @default.
- W2045979354 cites W1966514289 @default.
- W2045979354 cites W1966691535 @default.
- W2045979354 cites W1967028773 @default.
- W2045979354 cites W1976155534 @default.
- W2045979354 cites W1979064469 @default.
- W2045979354 cites W1979298709 @default.
- W2045979354 cites W1985542411 @default.
- W2045979354 cites W1986170265 @default.
- W2045979354 cites W1991621939 @default.
- W2045979354 cites W2016459867 @default.
- W2045979354 cites W2036095191 @default.
- W2045979354 cites W2043631520 @default.
- W2045979354 cites W2044214093 @default.
- W2045979354 cites W2044794194 @default.
- W2045979354 cites W2045508839 @default.
- W2045979354 cites W2046540171 @default.
- W2045979354 cites W2048803439 @default.
- W2045979354 cites W2052469052 @default.
- W2045979354 cites W2053875840 @default.
- W2045979354 cites W2058475680 @default.
- W2045979354 cites W2063766873 @default.
- W2045979354 cites W2077644437 @default.
- W2045979354 cites W2082434050 @default.
- W2045979354 cites W2083209367 @default.
- W2045979354 cites W2085558809 @default.
- W2045979354 cites W2095495437 @default.
- W2045979354 cites W2166862648 @default.
- W2045979354 cites W226838139 @default.
- W2045979354 cites W2324249672 @default.
- W2045979354 cites W2912671364 @default.
- W2045979354 cites W2952533743 @default.
- W2045979354 cites W2952965165 @default.
- W2045979354 cites W3004675425 @default.
- W2045979354 cites W3005432765 @default.
- W2045979354 cites W3138514238 @default.
- W2045979354 cites W4244068536 @default.
- W2045979354 doi "https://doi.org/10.1016/s0277-5387(02)01043-4" @default.
- W2045979354 hasPublicationYear "2002" @default.
- W2045979354 type Work @default.
- W2045979354 sameAs 2045979354 @default.
- W2045979354 citedByCount "9" @default.
- W2045979354 countsByYear W20459793542013 @default.
- W2045979354 crossrefType "journal-article" @default.
- W2045979354 hasAuthorship W2045979354A5057431845 @default.
- W2045979354 hasAuthorship W2045979354A5058540945 @default.
- W2045979354 hasAuthorship W2045979354A5060019697 @default.
- W2045979354 hasConcept C115624301 @default.
- W2045979354 hasConcept C116569031 @default.
- W2045979354 hasConcept C121332964 @default.
- W2045979354 hasConcept C145148216 @default.
- W2045979354 hasConcept C155647269 @default.
- W2045979354 hasConcept C161790260 @default.
- W2045979354 hasConcept C170493617 @default.
- W2045979354 hasConcept C178790620 @default.
- W2045979354 hasConcept C183882617 @default.
- W2045979354 hasConcept C185592680 @default.
- W2045979354 hasConcept C188328357 @default.
- W2045979354 hasConcept C2182769 @default.
- W2045979354 hasConcept C2777463227 @default.
- W2045979354 hasConcept C2777961443 @default.
- W2045979354 hasConcept C2779328170 @default.
- W2045979354 hasConcept C528581852 @default.
- W2045979354 hasConcept C542268612 @default.
- W2045979354 hasConcept C544153396 @default.
- W2045979354 hasConcept C55493867 @default.
- W2045979354 hasConcept C62520636 @default.
- W2045979354 hasConcept C71240020 @default.
- W2045979354 hasConcept C8010536 @default.
- W2045979354 hasConcept C94882840 @default.
- W2045979354 hasConceptScore W2045979354C115624301 @default.
- W2045979354 hasConceptScore W2045979354C116569031 @default.
- W2045979354 hasConceptScore W2045979354C121332964 @default.
- W2045979354 hasConceptScore W2045979354C145148216 @default.
- W2045979354 hasConceptScore W2045979354C155647269 @default.
- W2045979354 hasConceptScore W2045979354C161790260 @default.
- W2045979354 hasConceptScore W2045979354C170493617 @default.
- W2045979354 hasConceptScore W2045979354C178790620 @default.
- W2045979354 hasConceptScore W2045979354C183882617 @default.
- W2045979354 hasConceptScore W2045979354C185592680 @default.
- W2045979354 hasConceptScore W2045979354C188328357 @default.
- W2045979354 hasConceptScore W2045979354C2182769 @default.
- W2045979354 hasConceptScore W2045979354C2777463227 @default.
- W2045979354 hasConceptScore W2045979354C2777961443 @default.
- W2045979354 hasConceptScore W2045979354C2779328170 @default.
- W2045979354 hasConceptScore W2045979354C528581852 @default.
- W2045979354 hasConceptScore W2045979354C542268612 @default.
- W2045979354 hasConceptScore W2045979354C544153396 @default.
- W2045979354 hasConceptScore W2045979354C55493867 @default.