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- W2045984029 abstract "The gas-phase solvation reactions, X−(CH3OH)n−1 + CH3OH ⇌ X− (CH3OH)n, for X− F−, Br−, and I−, were studied using a pulsed electron beam high pressure mass spectrometer. The −ΔG°n−1,n values are in the order F− > Cl− > Br− > I−. However, the −ΔH°n−1,n values for Br− and I− decrease more gradually with n than those for F− and Cl− and they follow the order F− > Br− > Cl− with n ≥ 6. The first solvation shells of X− (CH3OH)n for X− F−, Cl−, and Br− seem to be completed with six CH3OH ligands. The −ΔH°n−1,n values for I− are almost independent of n and the completion of the first solvation shell does not take place up until n = 8. Owing to crowding in the inner shell, the −ΔS°n−1,n values for I− increase steadily with n. The differences between the cumulative thermochemical values, ΔG°0,n, ΔH°0,n, and TΔS°0,n, do not approach the differential thermochemical values for solution." @default.
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- W2045984029 date "1991-11-01" @default.
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- W2045984029 title "Solvation of halide ions with CH3OH in the gas phase" @default.
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- W2045984029 doi "https://doi.org/10.1016/0168-1176(91)85101-q" @default.
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