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- W2045984454 abstract "The standard molar Gibbs free energy of formation of Na2ZrO3(s) has been obtained by measuring equilibrium pressures of CO2 for the reaction: Na2CO3(s) + ZrO2(s) = Na2ZrO3(s) + CO2(g) by a static manometric method in the temperature range 878 to 1107 K. The CO2 pressures were least-squares analysed and can be represented by: lg(pkPa) = 7.470 − 7385.2(KT)±0.038, (878 to 1107 K). ΔfGmoNa2ZrO3(s) has been evaluated using ΔfGmos of CO2(g), ZrO2(s), and Na2CO3(s) and can be represented by ΔfGmo(Na2ZrO3, s, T)(kJ · mol−1) = −1676.27+0.348(TK)±1.1. Second- and third-law analyses yielded ΔfHmo(Na2ZrO3, s, 298.15 K) as −(1662.9±7.6) and −(1654.9±8.02) kJ · mol−1, respectively." @default.
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- W2045984454 date "1988-07-01" @default.
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- W2045984454 title "Standard molar Gibbs free energy of formation of Na2ZrO3(s)" @default.
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- W2045984454 doi "https://doi.org/10.1016/0021-9614(88)90064-x" @default.
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