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- W2045996881 abstract "Product studies were made using the Fourier transform infrared method in the uv (300–400-nm) photolysis of mixtures containing CH3SCH3, C2H5ONO, and NO in ppm concentrations in 700 torr of O2–N2 diluent. Methyl thionitrite, CH3SNO, arising from the reaction CH3S + NO, was detected as an intermediate product. In addition, the yields of the major sulfur-containing products SO2 and CH3SO3H coincided with those of the oxidation of the CH3S radicals generated directly by the photodissociation of CH3SNO. The formation of CH3S in the HO-initiated oxidation of CH3SCH3 in the presence of NO suggests a reaction scheme involving the H-abstraction reaction HO + CH3SCH3 → CH3SCH2 + H2O as the primary step." @default.
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- W2045996881 date "1983-07-01" @default.
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- W2045996881 title "An FTIR study of the mechanism for the reaction HO + CH3SCH3" @default.
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- W2045996881 doi "https://doi.org/10.1002/kin.550150706" @default.
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