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• W2046004556 abstract "Abstract SERS on silver sol has been demonstrated to be an attractive and simple spectroscopic tool for transition-metal complexes. The SERS spectra of [Cr(bpy) 3 ] 3+ on Ag sol are more similar to the solution Raman spectra of [Fe(bpy) 3 ] 2+ or [Ru(bpy) 3 ] 2+ than to that of [Cr(bpy) 3 ] 3+ , which gives a strong hint to a reduction of Cr(III) to Cr(II) on the silver colloid. The excitation with high-energy Cu-vapour laser pulses results in a clearly changed SERS spectrum, which can be explained by the superposition of the surface-enhanced excited-state Raman spectrum (SEERS) of [Cr(bpy) 3 ] 2+ and its surface-enhanced ground-state spectrum." @default.
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• W2046004556 date "1986-04-01" @default.
• W2046004556 modified "2023-09-27" @default.
• W2046004556 title "Surface-enhanced Raman scattering (sers) and surface-enhanced excited-state Raman scattering (seers) of a tris(2,2'-bipyridine)Cr complex adsorbed on colloidal silver" @default.
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• W2046004556 doi "https://doi.org/10.1016/0009-2614(86)85118-1" @default.
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