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- W2046006604 abstract "Ernest Davidson's contributions of potential energy surfaces for thermal reactions of organic compounds form an important body of scientific work. His pursuit, with Borden, of the methylenecyclopropane degenerate rearrangement involving the trimethylenemethane singlet biradical with planar and orthogonal species is a classic example that also touches on the Davidson-Borden characterization of open shell, pi conjugated biradicals as either disjoint or non-disjoint systems. In a related effort with vinylmethylenecyclopropane he not only calculated all reasonable stationary points for both the singlet and triplet species, but demonstrated the preference for a conrotatory-bevel closure of a cross-conjugated 1,5 singlet biradical. Further, he pursued the classic hydrocarbon 1,3 biradicals trimethylene and vinyltrimethylene, showing in the latter case that there are no intermediates on the potential energy surface. Thus the reaction appears to proceed from saddle point to saddle point by traversing coordinates ..." @default.
- W2046006604 created "2016-06-24" @default.
- W2046006604 creator A5053436844 @default.
- W2046006604 date "2002-02-10" @default.
- W2046006604 modified "2023-09-28" @default.
- W2046006604 title "A personal recollection of Ernest Roy Davidson's contributions to organic chemistry" @default.
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- W2046006604 doi "https://doi.org/10.1080/00268970110091673" @default.
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