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- W2046020187 abstract "Abstract Equations of the Alfrey-Price, Hammett, Bamford-Jenkins and Hoyland schemes are of one type. The Q - e scheme is the most widespread because of its simplicity and clarity and has now received theoretical substantiation in terms of the theory of molecular orbitals. The parameters of the scheme have a distinct physical meaning—they correlate with the energy of the localization, order and π -electron density of the monomer double bond. The values of the Q and e parameters of the monomers may be found by UV and 13 C NMR spectroscopy. The Q - e scheme remians a reliable instrument for the qualitative prediction of the relative activities of the monomers and their interpretation from the standpoint of the theory of chemical structure. The latest findings on the influence of selective sorption of monomers on the r 1 and r 2 magnitudes raise new tasks—specifying the parameters Q and e of the monomers and correct choice of the r 1 and r 2 values from the spectrum of the experimental values." @default.
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- W2046020187 date "1990-01-01" @default.
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- W2046020187 title "Current interpretation of the Q-e scheme. Review" @default.
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- W2046020187 doi "https://doi.org/10.1016/0032-3950(90)90001-m" @default.
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