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- W2046038102 abstract "Thermal as well as microwave mediated free radical degradation of Guar gum in to lower molecular weight fragments was studied. Swollen suspensions of guar flour, containing either potassium persulphate or hydrogen peroxide, in aqueous isopropyl alcohol were heated to effect depolymerisation. From the intrinsic viscosity of the resulting products, molecular weight was calculated using the Mark-Houwink equation. It was shown that both hydrogen peroxide and potassium persulphate degrade guar gum in a concentration dependent manner and persulphate appeared to reduce molecular weight more effectively than hydrogen peroxide. Microwave heating also promoted the degradation of guar gum and was much faster than conventional thermal reactions. Thus prepared lower molecular weight guars are also shown to have better film forming properties." @default.
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- W2046038102 date "2004-12-01" @default.
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- W2046038102 title "Free radical degradation of guar gum" @default.
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- W2046038102 doi "https://doi.org/10.1016/j.polymdegradstab.2004.05.017" @default.
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