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• W2046041892 abstract "Four di-CuII-substituted sandwich-type germanomolybdates, (H2en)2H7{[Na0.5(H2O)3.5]2[Cu2(β-Y-GeMo9O33)2]}·6H2O (1), (H2en)2H{[Na2.5(H2O)12]2[Cu(en)2][Cu2(β-Y-GeMo9O33)2]}·8H2O (2), [Na4(H2O)12]2H4[Cu2(β-Y-GeMo9O33)2]}·11H2O (3) and [Cu(en)2]2[Cu(en)2(H2O)]2{[Cu(en)2]2[Cu2(β-Y-GeMo9O33)2]}·8H2O (4) (en = ethylenediamine), have been prepared. It is interesting that 1–3 were obtained in the same aqueous solution reaction system but exhibited different structures: 1 displays a 0D structure, 2 shows an organic–inorganic 1D chain structure, while 3 displays a 2D network. 4 was synthesized under hydrothermal condition by the same reagents, which represents the first transition metal-sandwiched organic–inorganic 2D heteropolymolybdate." @default.
• W2046041892 created "2016-06-24" @default.
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• W2046041892 date "2012-01-01" @default.
• W2046041892 modified "2023-09-27" @default.
• W2046041892 title "Four di-CuII-substituted sandwich-type germanomolybdates obtained under different reaction conditions: from zero-dimensional to two-dimensional structure" @default.
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• W2046041892 doi "https://doi.org/10.1039/c2dt12491b" @default.
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