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• W2046043150 endingPage "139" @default.
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• W2046043150 abstract "The reactions of AgNO3, PhHgOAc and HgCl2 with Hmmtrz gave three new complexes, [Ag(mmtrz)(PPh3)2]·Hmmtrz (1), [Hg2(mmtrz)4(Hmmtrz)2] (2) and [Hg(mmtrz)2]n (3) (Hmmtrz = 3-mercapto-4-methyl-4H-1,2,4-triazole), which have been isolated and well characterised by CHN analyses, IR, NMR, single crystal X-ray and TG-DTA data. Complex 1 adopts a distorted trigonal planar arrangement in which Ag(I) is bonded through the thiolato sulfur atom of the mmtrz anion and two phosphorus atoms of PPh3, along with one unit of the ligand held via a weak Ag⋯S contact. Complex 2 has been formed by symmetrization or dimerisation in chloroform solution via the reaction 4[PhHgL]−[Hg2L4] + 2HgPh2. In the dimeric complex 2, each Hg(II) centre has a distorted tetrahedral geometry bonded through two thiolato sulfur atoms of two terminal ligands, one nitrogen and one thiol sulfur (SH) from a neutral bridging ligand, forming an eight-membered ring around two Hg(II) centers. The one dimensional metal–organic coordination polymer of complex 3 is obtained by the reaction of HgCl2 with Hmmtrz in methanol, in which Hg(II) adopts a tetrahedral geometry bonded through two thiolato sulfur and two nitrogen atoms from two ligands. Complexes 1 and 2 are stabilized by intermolecular π⋯π interactions. Supramolecular organisation through hydrogen bonding is present in these complexes. Complexes 1 and 3 are fluorescent materials upon excitation at 263 and 327 nm respectively, exhibiting a weak emission at 389 nm and a medium-strong emission at 421 nm as a consequence of intraligand π–π∗ transitions. The course of the thermal degradations of complexes 1 and 3 has been investigated by TG-DTA. Thermogravimetric analysis of complex 1 shows a single weight loss to give Ag2S, indicating that the complex might be useful as a precursor for the synthesis of pure Ag2S nanoparticles and thin films." @default.
• W2046043150 created "2016-06-24" @default.
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• W2046043150 date "2013-04-01" @default.
• W2046043150 modified "2023-10-16" @default.
• W2046043150 title "Mononuclear Ag(I), dinuclear and polymeric Hg(II) complexes of 3-mercapto-4-methyl-4H-1,2,4-triazole: Syntheses, spectral, X-ray, photoluminescence and thermal analysis" @default.
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• W2046043150 cites W1990717167 @default.
• W2046043150 cites W1991161714 @default.
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• W2046043150 cites W2005216254 @default.
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• W2046043150 cites W2016567958 @default.
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• W2046043150 cites W2020599041 @default.
• W2046043150 cites W2023048616 @default.
• W2046043150 cites W2034401365 @default.
• W2046043150 cites W2037456960 @default.
• W2046043150 cites W2038967919 @default.
• W2046043150 cites W2049022648 @default.
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• W2046043150 doi "https://doi.org/10.1016/j.poly.2013.02.035" @default.
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