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- W2046064672 abstract "Raman spectra of the spin-crossover complex [Fe(ptz)6](BF4)2 (ptz = 1-n-propyl-tetrazole) have been recorded at visible and IR exciting wavelengths as a function of temperature down to 5 K. Distinct Raman markers were associated with the spin-state change and the crystallographic phase-transition of the compound. This allows us to demonstrate that the light-induced exited spin-state trapping (LIESST) and the reverse-LIESST effects as well as the thermal relaxation of the photo-induced phase occur without crystallographic phase change in contrast to the thermal spin-crossover." @default.
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- W2046064672 date "2005-02-01" @default.
- W2046064672 modified "2023-09-30" @default.
- W2046064672 title "Decoupling of the molecular spin-state and the crystallographic phase in the spin-crossover complex [Fe(ptz)6](BF4)2 studied by Raman spectroscopy" @default.
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- W2046064672 doi "https://doi.org/10.1016/j.cplett.2004.12.078" @default.
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