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• W2046078275 abstract "Availability of highly reactive halogen ions at the surface of aerosols has tremendous implications for the atmospheric chemistry. Yet neither simulations, experiments, nor existing theories are able to provide a fully consistent description of the electrolyte-air interface. In this Letter a new theory is proposed which allows us to explicitly calculate the ionic density profiles, the surface tension, and the electrostatic potential difference across the solution-air interface. Predictions of the theory are compared to experiments and are found to be in excellent agreement. The theory also sheds new light on one of the oldest puzzles of physical chemistry--the Hofmeister effect." @default.
• W2046078275 created "2016-06-24" @default.
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• W2046078275 date "2009-12-17" @default.
• W2046078275 modified "2023-10-16" @default.
• W2046078275 title "Ions at the Air-Water Interface: An End to a Hundred-Year-Old Mystery?" @default.
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• W2046078275 doi "https://doi.org/10.1103/physrevlett.103.257802" @default.
• W2046078275 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20366288" @default.
• W2046078275 hasPublicationYear "2009" @default.
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