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- W2046114686 endingPage "1612" @default.
- W2046114686 startingPage "1585" @default.
- W2046114686 abstract "The direct proportionality of the intensification ΔA1/2 of the infrared (IR) proton stretching vibration (ν(XH)) band in the XH⋯Y hydrogen bond and its enthalpy, −ΔH=12.2 ΔA1/2, suggested by an ‘additive’ model of the effective charges of the XH and H⋯Y bonds, is discussed. Its universal validity is illustrated over a 200-fold energy range (0.3–60 kJ mol−1) for a large number of different XH⋯Y hydrogen bonds of different associates, from the great diversity of dimers to the continuous three-dimensional network of liquid water and ice. The contrasting behaviors of the νs-band intensification and its frequency shift, Δν, are compared." @default.
- W2046114686 created "2016-06-24" @default.
- W2046114686 creator A5088025145 @default.
- W2046114686 date "1999-07-01" @default.
- W2046114686 modified "2023-10-10" @default.
- W2046114686 title "Direct proportionality of the hydrogen bonding energy and the intensification of the stretching ν(XH) vibration in infrared spectra" @default.
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