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- W2046120899 abstract "Abstract Treatment of the species formed by deprotonation of the (η 5 -cyclopentadienyl-η 6 -tetraliniron) cation with the chiral alkyl nitrite (menthyl nitrite) yields the optically active (η5-cyclopentadienyl-η 6 -α-tetralonoximeiron)cation. Various parameters have been studied to see how the optical yield was affected. Hydrolysis of the oxime group gives the corresponding chiral ketone. The Stereoselectivity of the cathodic reduction of the cationic oxime and of the cationic ketone, in acidic medium, gives the optically active endo amine and the optically active endo alcohol. The optical yield of nitrosation (4 to 7%), the absolute configuration, and the specific rotation of the various intermediates have been deduced from rotation of the chiral 1-aminotetralin or of the chiral 1-tetralol obtained from the decomsosition of the corresponding complexes." @default.
- W2046120899 created "2016-06-24" @default.
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- W2046120899 date "1988-09-01" @default.
- W2046120899 modified "2023-09-25" @default.
- W2046120899 title "Prèparation de cations chiraux (η5-cyclopentadiènyl fer η6-arène)+ comportant une fonction oxime ou cètone en α du ligande arène, réduction électrochimique en amine ou en alcool optiquement actifs" @default.
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- W2046120899 doi "https://doi.org/10.1016/0022-328x(88)83123-1" @default.
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