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- W2046129427 abstract "Benzoyl fluoride exhibits a weak, discrete absorption system in the region 290 – 260 nm. Vibrational structure associated with the C6H5COF and C6D5COF isotopes has been analyzed in detail. The C6H5COF and C6D5COF origin bands lie at 35 685 and 35 829 cm−1, respectively. The intensity in the spectrum is principally associated with two progressions, ν′19, the breathing vibration of the benzene ring and ν′24, a COF in-plane bend, and sequence bands involving the COF torsion motion ν36. The C6H5COFC6D5COF ν19, ν24, and ν36 vibrational frequencies are respectively 1005/-, 376357, and 5755 cm−1 in the ground state and 950919, 348331, and 8985 cm−1 in the excited state. The barriers to rotation of the COF group are estimated from the torsional frequency data to be 1450 and 3450 cm−1 in the ground and excited electronic states, respectively." @default.
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- W2046129427 date "1980-11-01" @default.
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- W2046129427 title "The 280-nm absorption system of benzoyl fluoride" @default.
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- W2046129427 doi "https://doi.org/10.1016/0022-2852(80)90238-6" @default.
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