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• W2046143252 abstract "Abstract Excess molar volumes V m E and excess molar enthalpies H m E were measured as a function of mole fraction at T  =  303.15 K and atmospheric pressure for each of the mixtures {1-heptyne, or 1-octyne  +  tetramethylene sulfone (sulfolane)}. Excess molar volumes were also measured for mixtures of (1-hexyne  +  sulfolane). The results were compared in an attempt to investigate the interactions between the highly polar sulfolane molecule and the terminal proton of the alkynes. The H m E results were discussed in terms of the NRTL and Wilson models and were predicted from equimolar values of V m E by the Prigogine–Flory–Patterson (PFP) theory with a free volume contribution obtained from Flory’s equation of state model. The results were compared with the modified UNIFAC model. The description of H m E by the PFP theory was better than the prediction by the modified UNIFAC." @default.
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• W2046143252 date "2000-05-01" @default.
• W2046143252 modified "2023-09-25" @default.
• W2046143252 title "Excess molar volumes and enthalpies of (1-hexyne, or 1-heptyne, or 1-octyne + sulfolane) at the temperature 303.15 K" @default.
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• W2046143252 doi "https://doi.org/10.1006/jcht.1999.0618" @default.
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