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- W2046150753 abstract "Abstract The oxidation of d -myo-inositol (Myo) by CrVI yields the inosose and Cr3+ as final products when an excess of cyclitol over CrVI is used. The redox reaction takes place through the combination of CrVI → CrIV → CrII and CrVI → CrIV → CrIII pathways. Intermediacy of CrIV was evidenced by the detection of CrO 2 2 + , formed by reaction of CrII with O2. The EPR spectra show that five- and six-coordinated oxo-CrV intermediates are formed, with the cyclitol acting as bidentate ligand. Penta-coordinated oxo-CrV species are present at any [H+], whereas hexa-coordinated ones are only observed at pH" @default.
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- W2046150753 date "2007-01-01" @default.
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- W2046150753 title "Kinetics and mechanism of the chromic oxidation of myo-inositol" @default.
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- W2046150753 doi "https://doi.org/10.1016/j.poly.2006.08.003" @default.
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