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• W2046156797 abstract "The synthesis and characterization of new tris(carbene)borate ligand precursors containing substituted benzimidazol-2-ylidene and 1,3,4-triazol-2-ylidene donor groups, as well as a new tris(imidazol-2-ylidene)borate ligand precursor are reported. The relative donor strengths of the tris(carbene)borate ligands have been evaluated by the position of ν(NO) in four-coordinate {NiNO}10 complexes, and follow the order: imidazol-2-ylidene > benzimidazol-2-ylidene > 1,3,4-triazol-2-ylidene. There is a large variation in ν(NO), suggesting these ligands to have a wide range of donor strengths while maintaining a consistent ligand topology. All ligands are stronger donors than Tp* and Cp*." @default.
• W2046156797 created "2016-06-24" @default.
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• W2046156797 date "2012-11-09" @default.
• W2046156797 modified "2023-09-27" @default.
• W2046156797 title "Tris(carbene)borate Ligands Featuring Imidazole-2-ylidene, Benzimidazol-2-ylidene, and 1,3,4-Triazol-2-ylidene Donors. Evaluation of Donor Properties in Four-Coordinate {NiNO}¹⁰ Complexes" @default.
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• W2046156797 doi "https://doi.org/10.1021/ic301204b" @default.
• W2046156797 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3524973" @default.
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