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- W2046164102 abstract "Abstract We focus on the H 2 desorption properties of the 2NaBH 4 + MgH 2 system destabilized by different methods. Nanostructured powder mixtures were prepared by ball milling the starting hydrides and nanoconfined reactive composites were obtained by melting infiltration of the hydrides into a Si-based SBA-15 support. NbF 5 was tested as catalyst in both the preparations. Structural characterization by X Ray Diffraction and Transmission Electron Microscopy allowed evaluating the successful synthesis of SBA15 matrix, the microstructural features of ball milled and nanoconfined hydrides as well as the success of infiltration process. The evaluation of the sorption properties, by manometric Sievert-type apparatus and thermal desorption spectroscopy, revealed the efficiency of the hydride destabilization, obtained by the different routes, in decreasing the hydrogen release temperature and improving desorption kinetics." @default.
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- W2046164102 date "2012-09-01" @default.
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- W2046164102 title "Hydrogen storage in 2NaBH4+MgH2 mixtures: Destabilization by additives and nanoconfinement" @default.
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- W2046164102 doi "https://doi.org/10.1016/j.jallcom.2011.12.042" @default.
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