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- W2046178492 abstract "The agglomerate-of-spheres' model concerns the structure of participate battery electrodes, in particular the positive lead/acid battery electrode. This model consists of an agglomerate-of-spheres of the active material electrically connected by vase-shaped ‘necks’. It has been claimed that for electrodes made from non-stoichiometric compounds — in particular PbO2 electrodes — there exists a certain combination of neck-and-sphere dimensions which, by the way of the non-stoichiometry, is thermodynamically stable. In the present paper this situation is discussed from a rigorous thermodynamic point of view. It is found that no sphere-neck configuration exists, representing an equilibrium state." @default.
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- W2046178492 date "1997-05-01" @default.
- W2046178492 modified "2023-09-27" @default.
- W2046178492 title "On the thermodynamics of the agglomerate-of-spheres' model for the PbO2 electrode" @default.
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- W2046178492 doi "https://doi.org/10.1016/s0378-7753(96)02607-9" @default.
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