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- W2046179905 abstract "The reaction of HGaCl2 with 1-octene yields 1-octylgallium(III) dichloride in 77% yield, but with 2-octene a 2:1 mixture of 2- and 3-octylgallium dichloride(III) is obtained in 88% yield, and the reaction of E-stilbene gives an even more complex mixture. Hydrogallation of 1,4-diphenylbutadiene with HGaCl2 followed by hydrolysis yields 1,4-diphenylbutane in 53% yield. The reactions of diphenylacetylene and 4-octyne under the same conditions give E-stilbene and E-4-octene in 76% and 63% yield, respectively, while 1-octyne undergoes polymerization. 2-Benzoylstyrene (calcone) reacts with HGaCl2 to give, as the main product, a compound arising from 1,4-addition of the HGa bond across the enone system, together with a double hydrogallation product." @default.
- W2046179905 created "2016-06-24" @default.
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- W2046179905 date "1993-06-01" @default.
- W2046179905 modified "2023-10-12" @default.
- W2046179905 title "The reaction of hydrogallium(III) dichloride (HGaCl2) with olefines, acetylenes, and α,β-unsaturated ketones" @default.
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- W2046179905 doi "https://doi.org/10.1016/0022-328x(93)80319-7" @default.
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