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• W2046181048 abstract "A thermodynamic equilibrium sensor is proposed that measures the ratio of the number of elementary charges z to the mass m of charged solutes such as charged colloids and nanoparticles. The sensor comprises a small, membrane-encapsulated salt solution volume that absorbs neutral salt molecules in response to the release of mobile counter-ions by charge carriers in the surrounding suspension. The sensor state emerges as a limiting case of the equilibrium salt imbalance, and the ensuing osmotic pressure difference, between arbitrary salt and suspension volumes. A weight concentration of charge carriers c is predicted to significantly increase the sensor's salt number density from its initial value ρs,0 to ρRs, according to the relation (ρRs/ρs,0)(2)-1=zc/mρs,0, under the assumption that the mobile ions involved in the thermodynamic sensor-suspension equilibrium are ideal and homogeneously distributed." @default.
• W2046181048 created "2016-06-24" @default.
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• W2046181048 date "2015-01-01" @default.
• W2046181048 modified "2023-09-27" @default.
• W2046181048 title "A thermodynamic gauge for mobile counter-ions from colloids and nanoparticles" @default.
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• W2046181048 doi "https://doi.org/10.1039/c4fd00261j" @default.
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