FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046198269> ?p ?o ?g. }

• W2046198269 endingPage "9414" @default.
• W2046198269 startingPage "9406" @default.
• W2046198269 abstract "Abstract An axially chiral dihydroborepine with a binaphthyl backbone and a C 6 F 5 substituent at the boron atom was prepared by transmetalation from the corresponding tin precursor. This novel motif was structurally characterized by X‐ray diffraction analysis as its THF and its PhCN Lewis acid/base complex. 1 H NMR measurements at variable temperatures of the former adduct revealed a remarkable dynamic behavior in solution. Several more Lewis pairs with oxygen, nitrogen, carbon, and phosphorus σ‐donors were synthesized and analyzed by multinuclear NMR spectroscopy. The determination of the borane’s Lewis acidity with the Gutmann–Beckett method attests its substantial Lewis acidity [85 % with Et 3 PO as well as 74 % with Ph 3 PO relative to the parent B(C 6 F 5 ) 3 ]. Representative examples of SiH bond activation (carbonyl reduction and dehydrogenative SiO coupling) are included, demonstrating the chemical stability and the synthetic potential of the new chiral boron‐based Lewis acid." @default.
• W2046198269 created "2016-06-24" @default.
• W2046198269 creator A5002792140 @default.
• W2046198269 creator A5039921470 @default.
• W2046198269 creator A5077234233 @default.
• W2046198269 date "2011-07-05" @default.
• W2046198269 modified "2023-10-18" @default.
• W2046198269 title "An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity" @default.
• W2046198269 cites W1501319738 @default.
• W2046198269 cites W1539796472 @default.
• W2046198269 cites W1964740687 @default.
• W2046198269 cites W1964885234 @default.
• W2046198269 cites W1966296282 @default.
• W2046198269 cites W1967337848 @default.
• W2046198269 cites W1968670857 @default.
• W2046198269 cites W1971771722 @default.
• W2046198269 cites W1974203754 @default.
• W2046198269 cites W1977225494 @default.
• W2046198269 cites W1980565187 @default.
• W2046198269 cites W1981600895 @default.
• W2046198269 cites W1982214939 @default.
• W2046198269 cites W1987753766 @default.
• W2046198269 cites W1988451434 @default.
• W2046198269 cites W1994567008 @default.
• W2046198269 cites W1994616510 @default.
• W2046198269 cites W1995053726 @default.
• W2046198269 cites W2003050241 @default.
• W2046198269 cites W2003732742 @default.
• W2046198269 cites W2007026316 @default.
• W2046198269 cites W2010383964 @default.
• W2046198269 cites W2010797442 @default.
• W2046198269 cites W2012134512 @default.
• W2046198269 cites W2013468066 @default.
• W2046198269 cites W2013668323 @default.
• W2046198269 cites W2014725288 @default.
• W2046198269 cites W2015402899 @default.
• W2046198269 cites W2016869410 @default.
• W2046198269 cites W2017267600 @default.
• W2046198269 cites W2023299920 @default.
• W2046198269 cites W2023756162 @default.
• W2046198269 cites W2024664678 @default.
• W2046198269 cites W2026144804 @default.
• W2046198269 cites W2030380295 @default.
• W2046198269 cites W2031245685 @default.
• W2046198269 cites W2034151368 @default.
• W2046198269 cites W2036657192 @default.
• W2046198269 cites W2037253028 @default.
• W2046198269 cites W2037935642 @default.
• W2046198269 cites W2038861951 @default.
• W2046198269 cites W2039396938 @default.
• W2046198269 cites W2039521940 @default.
• W2046198269 cites W2042739813 @default.
• W2046198269 cites W2045914232 @default.
• W2046198269 cites W2046933565 @default.
• W2046198269 cites W2053540681 @default.
• W2046198269 cites W2057344624 @default.
• W2046198269 cites W2060137387 @default.
• W2046198269 cites W2061936071 @default.
• W2046198269 cites W2064998085 @default.
• W2046198269 cites W2068052889 @default.
• W2046198269 cites W2068823643 @default.
• W2046198269 cites W2071033467 @default.
• W2046198269 cites W2074225716 @default.
• W2046198269 cites W2079211064 @default.
• W2046198269 cites W2081858380 @default.
• W2046198269 cites W2093161659 @default.
• W2046198269 cites W2094635504 @default.
• W2046198269 cites W2103482827 @default.
• W2046198269 cites W2107559437 @default.
• W2046198269 cites W2109746413 @default.
• W2046198269 cites W2110128916 @default.
• W2046198269 cites W2115378983 @default.
• W2046198269 cites W2120749361 @default.
• W2046198269 cites W2121455509 @default.
• W2046198269 cites W2128608980 @default.
• W2046198269 cites W2131350133 @default.
• W2046198269 cites W2136252185 @default.
• W2046198269 cites W2141120537 @default.
• W2046198269 cites W2141743815 @default.
• W2046198269 cites W2143453620 @default.
• W2046198269 cites W2147148421 @default.
• W2046198269 cites W2148066840 @default.
• W2046198269 cites W2161528588 @default.
• W2046198269 cites W2168879305 @default.
• W2046198269 cites W2170733286 @default.
• W2046198269 cites W2171180989 @default.
• W2046198269 cites W2315752527 @default.
• W2046198269 cites W2329068187 @default.
• W2046198269 cites W2497812861 @default.
• W2046198269 cites W2950003831 @default.
• W2046198269 cites W2951913084 @default.
• W2046198269 cites W2952360739 @default.
• W2046198269 cites W2952414198 @default.
• W2046198269 cites W4238092974 @default.
• W2046198269 cites W4240952254 @default.
• W2046198269 cites W4243459497 @default.
• W2046198269 cites W4243555454 @default.
• W2046198269 cites W4251332763 @default.

• next