FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046201877> ?p ?o ?g. }

• W2046201877 endingPage "8476" @default.
• W2046201877 startingPage "8470" @default.
• W2046201877 abstract "Water-induced chain dynamics alterations are of paramount importance in many protein-based polymers because they determine and affect to a great extent the temperature dependence of the end properties. In this study, the thermal behavior of the reversible unfolding and refolding of poly(Val-Pro-Gly-Val-Gly) and poly(Val-Pro-Ala-Val-Gly) and of their concurrent dehydration and hydration processes has been studied by differential scanning calorimetry (DSC) and turbidimetry. Contrary to the good reversibility shown by poly(Val-Pro-Gly-Val-Gly), the substitution of glycine by alanine in poly(Val-Pro-Ala-Val-Gly) perturbed to a large extent the process of chain unfolding. For the latter polymer, it was found that both chain unfolding and rehydration processes take place at large undercoolings, suggesting that both events occur far from equilibrium conditions and, therefore, are strongly dominated by kinetics. In this context, the existence of an hydration excess with a kinetic rather than a thermodynamic nature is a remarkable observation. The kinetics of folding and unfolding were also studied by using an isoconversional method of kinetic analysis, i.e., the model-free Friedmand's isoconversional method. As expected, the kinetics of the solvation of nonpolar moieties for both polymers indicated a complex and multistep process. Again, poly(Val-Pro-Ala-Val-Gly) showed a quite different pattern characterized by an acute hysteresis behavior which seems to govern the hydration process for this polymer. The differences observed between both polymers have been interpreted in terms of the hindrance provided by the methyl group in alanine during temperature-induced chain dynamics." @default.
• W2046201877 created "2016-06-24" @default.
• W2046201877 creator A5003497084 @default.
• W2046201877 creator A5025058277 @default.
• W2046201877 creator A5038790997 @default.
• W2046201877 creator A5044324587 @default.
• W2046201877 creator A5066600157 @default.
• W2046201877 creator A5066650429 @default.
• W2046201877 date "2003-10-11" @default.
• W2046201877 modified "2023-10-17" @default.
• W2046201877 title "Thermal Behavior and Kinetic Analysis of the Chain Unfolding and Refolding and of the Concomitant Nonpolar Solvation and Desolvation of Two Elastin-like Polymers" @default.
• W2046201877 cites W133369315 @default.
• W2046201877 cites W1970147513 @default.
• W2046201877 cites W1976481362 @default.
• W2046201877 cites W1978749849 @default.
• W2046201877 cites W1985204165 @default.
• W2046201877 cites W1988900301 @default.
• W2046201877 cites W1994146881 @default.
• W2046201877 cites W1996050758 @default.
• W2046201877 cites W2016807719 @default.
• W2046201877 cites W2022224158 @default.
• W2046201877 cites W2034173639 @default.
• W2046201877 cites W2050175460 @default.
• W2046201877 cites W2056296989 @default.
• W2046201877 cites W2064495229 @default.
• W2046201877 cites W2083726217 @default.
• W2046201877 cites W2084777440 @default.
• W2046201877 cites W2088362306 @default.
• W2046201877 cites W2097083668 @default.
• W2046201877 cites W2120183443 @default.
• W2046201877 cites W2124506765 @default.
• W2046201877 cites W2318742334 @default.
• W2046201877 cites W4300611374 @default.
• W2046201877 doi "https://doi.org/10.1021/ma034572q" @default.
• W2046201877 hasPublicationYear "2003" @default.
• W2046201877 type Work @default.
• W2046201877 sameAs 2046201877 @default.
• W2046201877 citedByCount "77" @default.
• W2046201877 countsByYear W20462018772012 @default.
• W2046201877 countsByYear W20462018772013 @default.
• W2046201877 countsByYear W20462018772014 @default.
• W2046201877 countsByYear W20462018772015 @default.
• W2046201877 countsByYear W20462018772016 @default.
• W2046201877 countsByYear W20462018772017 @default.
• W2046201877 countsByYear W20462018772018 @default.
• W2046201877 countsByYear W20462018772019 @default.
• W2046201877 countsByYear W20462018772020 @default.
• W2046201877 countsByYear W20462018772021 @default.
• W2046201877 countsByYear W20462018772022 @default.
• W2046201877 crossrefType "journal-article" @default.
• W2046201877 hasAuthorship W2046201877A5003497084 @default.
• W2046201877 hasAuthorship W2046201877A5025058277 @default.
• W2046201877 hasAuthorship W2046201877A5038790997 @default.
• W2046201877 hasAuthorship W2046201877A5044324587 @default.
• W2046201877 hasAuthorship W2046201877A5066600157 @default.
• W2046201877 hasAuthorship W2046201877A5066650429 @default.
• W2046201877 hasConcept C119599485 @default.
• W2046201877 hasConcept C121332964 @default.
• W2046201877 hasConcept C127413603 @default.
• W2046201877 hasConcept C148093993 @default.
• W2046201877 hasConcept C148898269 @default.
• W2046201877 hasConcept C151730666 @default.
• W2046201877 hasConcept C178790620 @default.
• W2046201877 hasConcept C185592680 @default.
• W2046201877 hasConcept C188027245 @default.
• W2046201877 hasConcept C2776545253 @default.
• W2046201877 hasConcept C2779343474 @default.
• W2046201877 hasConcept C32909587 @default.
• W2046201877 hasConcept C39519442 @default.
• W2046201877 hasConcept C521977710 @default.
• W2046201877 hasConcept C62520636 @default.
• W2046201877 hasConcept C8010536 @default.
• W2046201877 hasConcept C86803240 @default.
• W2046201877 hasConcept C97355855 @default.
• W2046201877 hasConceptScore W2046201877C119599485 @default.
• W2046201877 hasConceptScore W2046201877C121332964 @default.
• W2046201877 hasConceptScore W2046201877C127413603 @default.
• W2046201877 hasConceptScore W2046201877C148093993 @default.
• W2046201877 hasConceptScore W2046201877C148898269 @default.
• W2046201877 hasConceptScore W2046201877C151730666 @default.
• W2046201877 hasConceptScore W2046201877C178790620 @default.
• W2046201877 hasConceptScore W2046201877C185592680 @default.
• W2046201877 hasConceptScore W2046201877C188027245 @default.
• W2046201877 hasConceptScore W2046201877C2776545253 @default.
• W2046201877 hasConceptScore W2046201877C2779343474 @default.
• W2046201877 hasConceptScore W2046201877C32909587 @default.
• W2046201877 hasConceptScore W2046201877C39519442 @default.
• W2046201877 hasConceptScore W2046201877C521977710 @default.
• W2046201877 hasConceptScore W2046201877C62520636 @default.
• W2046201877 hasConceptScore W2046201877C8010536 @default.
• W2046201877 hasConceptScore W2046201877C86803240 @default.
• W2046201877 hasConceptScore W2046201877C97355855 @default.
• W2046201877 hasIssue "22" @default.
• W2046201877 hasLocation W20462018771 @default.
• W2046201877 hasOpenAccess W2046201877 @default.
• W2046201877 hasPrimaryLocation W20462018771 @default.
• W2046201877 hasRelatedWork W1984761979 @default.
• W2046201877 hasRelatedWork W1988875377 @default.

• next