FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046203399> ?p ?o ?g. }

• W2046203399 endingPage "1752" @default.
• W2046203399 startingPage "1738" @default.
• W2046203399 abstract "Four scandium phosphate-based structures have been prepared hydrothermally in the presence of the primary diamines ethylenediamine and diaminobutane and the primary amine cyclohexylamine and characterised by single crystal and powder X-ray diffraction, 31P and 45Sc solid-state MAS NMR and chemical analysis. Charge balancing protons in the structures are located using bond valence sum calculations and postulated hydrogen bonding networks. Compound 1, [(H3NC2H4NH3)3][Sc3(OH)2(PO4)2(HPO4)3(H2PO4)], P1¯, a=5.4334(6), b=8.5731(9), c=16.3022(18)Å, α=79.732(4), β=83.544(4), γ=80.891(5)°, Z=2, is built up of scandium phosphate ribbons, based on trimers of ScO6 octahedra linked by OH groups. These trimers are joined through phosphate groups bound through three oxygens, and are decorated by phosphate groups linked by a single oxygen atom. The ribbons are arranged parallel to the a-axis and linked one to another by fully protonated ethylenediammonium ions. Compounds 2, [(H3NC4H8NH3)3][(Sc(OH2))6Sc2(HPO4)12(PO4)2], P3¯, a=13.8724(3), c=9.4351(11)Å, Z=1, and 3, [(H3NC4H8NH3)2(H3O)][Sc5F4(HPO4)8], C2/m, a=12.8538(4), b=14.9106(4), c=10.1906(3)Å, β=101.17(9)°, Z=2, were prepared using diaminobutane as the organic template in the absence and presence, respectively, of fluoride ions in the gel. Compound 2 has a pillared layered structure, in which ScO6 octahedra are linked by three vertices of hydrogenphosphate groups into sheets and the sheets pillared by ScO6 octahedra to give a three-dimensionally connected framework isostructural with a previously reported iron(III) hydrogenphosphate. The protonated diaminobutane molecules occupy cavities between the layers. Compound 3 has a layered structure in which isolated ScO6 octahedra and tetrameric arrangements of ScO4F2 octahedra, the latter linked in squares through fluoride ions, are connected by phosphate tetrahedra that share two or three oxygens with scandium atoms. In this structure, the protonated diaminobutane molecules connect the layers, the -NH3+ groups fitting into recesses in the layers. Compound 4, [(C6H11NH3)][ScF(HPO4)(H2PO4)], Pbca, a=7.650(3), b=12.867(5), c=26.339(11)Å, Z=8, the first scandium phosphate to be prepared with a monoamine, is also a layered solid. In this case, the layers contain single chains of ScO4F2 octahedra which share fluoride ions in trans positions. Phosphate tetrahedra bridge across scandiums via two of their four oxygens, both within the same chain and also to neighbouring chains to make up the layer. The protonated amine groups of the cyclohexylamine molecules achieve close contact with phosphates of the layer, while the cyclohexyl moieties, which are in the chair configuration, project into the interlayer space." @default.
• W2046203399 created "2016-06-24" @default.
• W2046203399 creator A5007889938 @default.
• W2046203399 creator A5049970193 @default.
• W2046203399 creator A5055432131 @default.
• W2046203399 creator A5064022614 @default.
• W2046203399 date "2005-06-01" @default.
• W2046203399 modified "2023-09-29" @default.
• W2046203399 title "Hydrothermal synthesis and structure of organically templated chain, layered and framework scandium phosphates" @default.
• W2046203399 cites W1945872785 @default.
• W2046203399 cites W1964874009 @default.
• W2046203399 cites W1974089223 @default.
• W2046203399 cites W1974376077 @default.
• W2046203399 cites W1974864685 @default.
• W2046203399 cites W1975190552 @default.
• W2046203399 cites W1982900948 @default.
• W2046203399 cites W1999547216 @default.
• W2046203399 cites W2016395181 @default.
• W2046203399 cites W2032778219 @default.
• W2046203399 cites W2064840285 @default.
• W2046203399 cites W2085827305 @default.
• W2046203399 cites W2143324574 @default.
• W2046203399 cites W2167590372 @default.
• W2046203399 cites W2949136965 @default.
• W2046203399 cites W2951245351 @default.
• W2046203399 cites W2951607465 @default.
• W2046203399 cites W2953386377 @default.
• W2046203399 doi "https://doi.org/10.1016/j.jssc.2005.03.012" @default.
• W2046203399 hasPublicationYear "2005" @default.
• W2046203399 type Work @default.
• W2046203399 sameAs 2046203399 @default.
• W2046203399 citedByCount "30" @default.
• W2046203399 countsByYear W20462033992013 @default.
• W2046203399 countsByYear W20462033992015 @default.
• W2046203399 countsByYear W20462033992017 @default.
• W2046203399 countsByYear W20462033992018 @default.
• W2046203399 countsByYear W20462033992022 @default.
• W2046203399 countsByYear W20462033992023 @default.
• W2046203399 crossrefType "journal-article" @default.
• W2046203399 hasAuthorship W2046203399A5007889938 @default.
• W2046203399 hasAuthorship W2046203399A5049970193 @default.
• W2046203399 hasAuthorship W2046203399A5055432131 @default.
• W2046203399 hasAuthorship W2046203399A5064022614 @default.
• W2046203399 hasConcept C112887158 @default.
• W2046203399 hasConcept C115624301 @default.
• W2046203399 hasConcept C127313418 @default.
• W2046203399 hasConcept C131779359 @default.
• W2046203399 hasConcept C145148216 @default.
• W2046203399 hasConcept C156622251 @default.
• W2046203399 hasConcept C165205528 @default.
• W2046203399 hasConcept C178790620 @default.
• W2046203399 hasConcept C179104552 @default.
• W2046203399 hasConcept C185592680 @default.
• W2046203399 hasConcept C198819137 @default.
• W2046203399 hasConcept C2776871784 @default.
• W2046203399 hasConcept C2777132085 @default.
• W2046203399 hasConcept C2778620993 @default.
• W2046203399 hasConcept C2780728571 @default.
• W2046203399 hasConcept C30095370 @default.
• W2046203399 hasConcept C32909587 @default.
• W2046203399 hasConcept C551831248 @default.
• W2046203399 hasConcept C71240020 @default.
• W2046203399 hasConcept C8010536 @default.
• W2046203399 hasConceptScore W2046203399C112887158 @default.
• W2046203399 hasConceptScore W2046203399C115624301 @default.
• W2046203399 hasConceptScore W2046203399C127313418 @default.
• W2046203399 hasConceptScore W2046203399C131779359 @default.
• W2046203399 hasConceptScore W2046203399C145148216 @default.
• W2046203399 hasConceptScore W2046203399C156622251 @default.
• W2046203399 hasConceptScore W2046203399C165205528 @default.
• W2046203399 hasConceptScore W2046203399C178790620 @default.
• W2046203399 hasConceptScore W2046203399C179104552 @default.
• W2046203399 hasConceptScore W2046203399C185592680 @default.
• W2046203399 hasConceptScore W2046203399C198819137 @default.
• W2046203399 hasConceptScore W2046203399C2776871784 @default.
• W2046203399 hasConceptScore W2046203399C2777132085 @default.
• W2046203399 hasConceptScore W2046203399C2778620993 @default.
• W2046203399 hasConceptScore W2046203399C2780728571 @default.
• W2046203399 hasConceptScore W2046203399C30095370 @default.
• W2046203399 hasConceptScore W2046203399C32909587 @default.
• W2046203399 hasConceptScore W2046203399C551831248 @default.
• W2046203399 hasConceptScore W2046203399C71240020 @default.
• W2046203399 hasConceptScore W2046203399C8010536 @default.
• W2046203399 hasIssue "6" @default.
• W2046203399 hasLocation W20462033991 @default.
• W2046203399 hasOpenAccess W2046203399 @default.
• W2046203399 hasPrimaryLocation W20462033991 @default.
• W2046203399 hasRelatedWork W1977796743 @default.
• W2046203399 hasRelatedWork W2046203399 @default.
• W2046203399 hasRelatedWork W2074744498 @default.
• W2046203399 hasRelatedWork W2087080763 @default.
• W2046203399 hasRelatedWork W2121789822 @default.
• W2046203399 hasRelatedWork W2348517428 @default.
• W2046203399 hasRelatedWork W2353120191 @default.
• W2046203399 hasRelatedWork W2357880472 @default.
• W2046203399 hasRelatedWork W2950825992 @default.
• W2046203399 hasRelatedWork W4249168586 @default.
• W2046203399 hasVolume "178" @default.

• next