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• W2046219687 abstract "Abstract A ligand containing the thiazolo[5,4‐ d ]thiazole (TzTz) core (acceptor) with terminal triarylamine moieties (donors), N,N ′‐(thiazolo[5,4‐ d ]thiazole‐2,5‐diylbis(4,1‐phenylene))bis( N ‐(pyridine‐4‐yl)pyridin‐4‐amine ( 1 ), was designed as a donor–acceptor system for incorporation into electronically active metal–organic frameworks (MOFs). The capacity for the ligand to undergo multiple sequential oxidation and reduction processes was examined using UV/Vis‐near‐infrared spectroelectrochemistry (UV/Vis‐NIR SEC) in combination with DFT calculations. The delocalized nature of the highest occupied molecular orbital (HOMO) was found to inhibit charge‐transfer interactions between the terminal triarylamine moieties upon oxidation, whereas radical species localized on the TzTz core were formed upon reduction. Conversion of 1 to diamagnetic 2+ and 4+ species resulted in marked changes in the emission spectra. Incorporation of this highly delocalized multi‐electron donor–acceptor ligand into a new two‐dimensional MOF, [Zn(NO 3 ) 2 ( 1 )] ( 2 ), resulted in an inhibition of the oxidation processes, but retention of the reduction capability of 1 . Changes in the electrochemistry of 1 upon integration into 2 are broadly consistent with the geometric and electronic constraints enforced by ligation." @default.
• W2046219687 created "2016-06-24" @default.
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• W2046219687 date "2014-10-24" @default.
• W2046219687 modified "2023-10-18" @default.
• W2046219687 title "Experimental and Computational Studies of a Multi-Electron Donor-Acceptor Ligand Containing the Thiazolo[5,4-<i>d</i>]thiazole Core and its Incorporation into a Metal-Organic Framework" @default.
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• W2046219687 doi "https://doi.org/10.1002/chem.201405089" @default.
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