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- W2046261787 abstract "Abstract The reagent Me3Si-L is versatile for conversion of M-Cl bonds into metal -imidazolates. Reactions with RuCl3., and [Ru(Ph3E)2Cl3(MeOH)] yield [RuClL2] and [Ru(Ph3E) 2L3] (E = P or As; L = imidazolate, Iz or 2-methylimidazolate, Melz) respectively, whereas [Ru(Ph3P)3Cl2] affords [Ru(Ph3P)2L2]. The stoichiometry of the compounds is consistent with the observed analytical data. The i. r. and C. V.-visible spectroscopic, conductivity and magnetic susceptibility measurement data indicate oligomerization with imidazolate bridging via the pyridyl nitrogen resulting in stable octahedral configurations around the ruthenium ion." @default.
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- W2046261787 date "1993-05-01" @default.
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- W2046261787 title "Synthetic Versatility of N-Trimethylsilyl-imidazole and N-Trimethylsilyl-2-methylimidazole as Reagents for the Preparation of Metal-Imidazolates. Physico-Chemical Studies on Imidazolate Bridged Ru(II) and Ru(III) Derivatives" @default.
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- W2046261787 doi "https://doi.org/10.1080/15533179308016854" @default.
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