Matches in SemOpenAlex for { <https://semopenalex.org/work/W2046269106> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2046269106 endingPage "124" @default.
- W2046269106 startingPage "121" @default.
- W2046269106 abstract "Trace organic micropollutants have adverse effects on human health and ecosystem at low concentrations. In this study, feasibility of new catalysts for oxidation of organic micropollutants was investigated. Iron tetrasulfophthalocyanine (FeTsPc) has been immobilized on the surface of functionalized MCF (mesocellular silica form)-NH 2 and MCM-41 mesoporous silicas by means of chemical bonding to ammosilane groups. MCF, prepared by precipitation from a micellar solution, consisted of unit cells which had internal void (~20 nm) and pores (~11 nm). NH 2 -functional groups were added to the surface of MCF and MCM-41 using (3-aminopropyl)triethoxysilane (APTES). 1-ethyl-3-(3’dimethylaminopropyl)carbodiimide (WSC) was used as a coupling agent. N-hydroxysuccinimide (NHS) was added during the reaction to improve the efficiency of amination. The prepared materials, FeTsPc/NH2-MCF and FeTsPc/NH2-MCM-41, were characterized by UV-DRS (diffuse reflectance UV-vis spectroscopy) and FT-IR. Bisphenol-A (BPA) was chosen as a model micropollutant. The catalytic activities of the supported Fe-TsPc were examined by the oxidation of BPA in the presence of hydroperoxide. The amount of immobilized FeTsPc and the specific reactivity were also analyzed to provide quantitative evaluation of the catalysts. The results indicated that the FeTsPc/NH2-MCM-41 showed higher activity and durability in the liquid-phase oxidation of BPA under mild condition compared with the FeTsPc/NH2-MCF and unsupported catalyst." @default.
- W2046269106 created "2016-06-24" @default.
- W2046269106 creator A5039274339 @default.
- W2046269106 creator A5066615255 @default.
- W2046269106 creator A5085320547 @default.
- W2046269106 date "2011-07-01" @default.
- W2046269106 modified "2023-10-05" @default.
- W2046269106 title "Immobilization of Iron Tetrasulfophthalocyanine on MCF-NH2 and MCM-41 Mesoporous Silicas" @default.
- W2046269106 cites W119500198 @default.
- W2046269106 cites W1966489607 @default.
- W2046269106 cites W1987230140 @default.
- W2046269106 cites W2091848665 @default.
- W2046269106 doi "https://doi.org/10.4028/www.scientific.net/msf.695.121" @default.
- W2046269106 hasPublicationYear "2011" @default.
- W2046269106 type Work @default.
- W2046269106 sameAs 2046269106 @default.
- W2046269106 citedByCount "0" @default.
- W2046269106 crossrefType "journal-article" @default.
- W2046269106 hasAuthorship W2046269106A5039274339 @default.
- W2046269106 hasAuthorship W2046269106A5066615255 @default.
- W2046269106 hasAuthorship W2046269106A5085320547 @default.
- W2046269106 hasConcept C13965031 @default.
- W2046269106 hasConcept C156328458 @default.
- W2046269106 hasConcept C161790260 @default.
- W2046269106 hasConcept C175583648 @default.
- W2046269106 hasConcept C178790620 @default.
- W2046269106 hasConcept C179104552 @default.
- W2046269106 hasConcept C185592680 @default.
- W2046269106 hasConcept C192562407 @default.
- W2046269106 hasConcept C2777496208 @default.
- W2046269106 hasConcept C65165184 @default.
- W2046269106 hasConcept C82776694 @default.
- W2046269106 hasConceptScore W2046269106C13965031 @default.
- W2046269106 hasConceptScore W2046269106C156328458 @default.
- W2046269106 hasConceptScore W2046269106C161790260 @default.
- W2046269106 hasConceptScore W2046269106C175583648 @default.
- W2046269106 hasConceptScore W2046269106C178790620 @default.
- W2046269106 hasConceptScore W2046269106C179104552 @default.
- W2046269106 hasConceptScore W2046269106C185592680 @default.
- W2046269106 hasConceptScore W2046269106C192562407 @default.
- W2046269106 hasConceptScore W2046269106C2777496208 @default.
- W2046269106 hasConceptScore W2046269106C65165184 @default.
- W2046269106 hasConceptScore W2046269106C82776694 @default.
- W2046269106 hasLocation W20462691061 @default.
- W2046269106 hasOpenAccess W2046269106 @default.
- W2046269106 hasPrimaryLocation W20462691061 @default.
- W2046269106 hasRelatedWork W2019916738 @default.
- W2046269106 hasRelatedWork W2026199022 @default.
- W2046269106 hasRelatedWork W2074421021 @default.
- W2046269106 hasRelatedWork W2080786335 @default.
- W2046269106 hasRelatedWork W2120731426 @default.
- W2046269106 hasRelatedWork W2332878934 @default.
- W2046269106 hasRelatedWork W2378594165 @default.
- W2046269106 hasRelatedWork W2603130584 @default.
- W2046269106 hasRelatedWork W3143388342 @default.
- W2046269106 hasRelatedWork W4205546906 @default.
- W2046269106 hasVolume "695" @default.
- W2046269106 isParatext "false" @default.
- W2046269106 isRetracted "false" @default.
- W2046269106 magId "2046269106" @default.
- W2046269106 workType "article" @default.