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- W2046272017 abstract "X-ray Rietveld analysis was performed to study the structural aspects of the different reduction/reoxidation behavior between Ln2O2SO4 and Ln2O2S (Ln = La and Pr). The two oxysulfates, Ln2O2SO4, and their reduced forms, Ln2O2S, are composed of alternative stacking of Ln2O22+ and SO42− or S2−. Not only interatomic distances but also bond angles of La2O2S and Pr2O2S were very similar. By contrast, a noticeable difference was observed for the oxysulfate, i.e., the S–O distances and the O–S–O angles, suggesting that larger distortion in the SO4 unit is a possible reason for the faster reduction of Pr2O2SO4 compared to La2O2SO4." @default.
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- W2046272017 date "2008-02-01" @default.
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- W2046272017 title "X-ray structural study on the different redox behavior of La and Pr oxysulfates/oxysulfides" @default.
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- W2046272017 doi "https://doi.org/10.1016/j.jallcom.2007.04.145" @default.
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