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- W2046282909 abstract "1,5-dimethylpolyphenylenoxide was brominated with NBS up to a substitution degree of 80%. The brominated PPO (BrPPO) was cross-linked with DABCO to a covalent cross-linked membrane. To investigate the influence of the size of the network, additional diiodobutane (DIB) was used. It could be determined that the ion conductivity (Cl−) with additional DIB rises from 2.3 mS/cm to 5.4 mS/cm despite a higher hydrophobicity of the DIB membranes. An IEC around 1 meq/g was reached and the methanol uptake was lower than 20%. The alkaline stability was investigated at 90 °C in 1 M KOH and all membranes showed a constant stable behaviour. The first DMFC measurement using a non precious FeCo/C catalyst on the cathode led to an excellent performance of 132 mW/cm2." @default.
- W2046282909 created "2016-06-24" @default.
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- W2046282909 date "2013-01-01" @default.
- W2046282909 modified "2023-09-23" @default.
- W2046282909 title "The application of covalently cross-linked BrPPO as AEM in alkaline DMFC" @default.
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- W2046282909 doi "https://doi.org/10.1016/j.memsci.2012.09.022" @default.
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