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- W2046286185 abstract "Abstract Successive titrations with base and acid using one solution yielded evidence that the relatively sharp transition to higher OH/Al values at pH≈ 6 may be caused, in part, by the formation of a relatively stable dispersion of a polynuclear species with OH/Al in the range 2.5 ± 3. Surface or edge site deprotonation of this species can be used to explain the OH/Al versus pH curve above pH ≈ 6. Destabilization of a polynuclear species by charge reduction through surface site deprotonation may control the formation of the visible aluminum hydroxide precipitate at pH > 6.5. The species/precipitate with OH/Al > 2.5 dissolves very slowly with acid addition. Dissolution occurred at a pH (4.9) which was significantly lower than the pH at which the species was formed and lower than the pH at which it apparently had aggregated to form the precipitate." @default.
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- W2046286185 date "1990-08-01" @default.
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- W2046286185 title "Surface ionization of polynuclear species in Al(III) hydrolysis—I. Titration results" @default.
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