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- W2046291187 abstract "The spin exchange interactions of the vanadium oxides AV4O9 (A=Ca, Sr, Cs2, and NH2(CH2)4NH2) were examined by calculating the spin orbital interaction energies of their spin dimers based on the extended Hückel method. The temperature Tmax at which the magnetic susceptibility maximum occurs in AV4O9 (A=Ca, Sr, Cs2, and NH2(CH2)4NH2) shows a wide variation (from 30 to 600 K) and increases in the order [NH2(CH2)4NH2]V4O9<CaV4O9<Cs2V4O9. The susceptibility at Tmax increases in the opposite order, and the room temperature susceptibility of [NH2(CH2)4NH2]V4O9 is about twice as high as the maximum susceptibility of CaV4O9. These observations were examined by estimating the magnetic excitation energies of the strongly interacting spin units of AV4O9." @default.
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- W2046291187 date "2000-09-01" @default.
- W2046291187 modified "2023-09-25" @default.
- W2046291187 title "Spin Dimer Analysis of the Spin Exchange Interactions of the Vanadium Oxides AV4O9 (A=Ca, Sr, Cs2, NH2(CH2)4NH2)" @default.
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- W2046291187 doi "https://doi.org/10.1006/jssc.2000.8753" @default.
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